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Putting batteries in the freezer or refrigerator doesn't necessarily prolong their life

Alkaline batteries stored at "room temperature" self discharge at a rate of less than two percent per year. So normally refrigerating or freezing them will only help maintain their charge by a tiny amount. Hardly worth the effort of chilling them. However, if alkaline batteries are stored at higher temperatures they will start to lose capacity much quicker. At 85 degrees F they only lose about 5% per year, but at 100 degrees they lose 25% per year. So if you live in a very hot climate or are storing your batteries in a very hot location, it may be worthwhile for you to store your alkaline batteries in a refrigerator instead.

NiMH and NiCd batteries self discharge at a MUCH faster rate than alkaline batteries. In fact, at "room temperature" (about 70 degrees F) NiMH and NiCD batteries will self discharge a few percent PER DAY. Storing them at lower temperatures will slow their self discharge rate dramatically. NiMH batteries stored at freezing will retain over 90% of their charge for full month. So it might make sense to store them in a freezer. If you do, it's best to bring them back to room temperature before using them. Even if you don't freeze your NiMH batteries after charging them, you should store them in a cool place to minimize their self discharge.

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